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Enhanced Electro-optical Properties of Low Viscous Nematic Liquid Crystal Doped with Mixed Phase Anatase/Rutile TiO2 Nanoparticles for Display Applications

Received: 13 June 2021    Accepted: 28 June 2021    Published: 6 July 2021
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Abstract

Organic–inorganic composite based on liquid crystalline and TiO2 nanoparticles were obtained and investigated taking into account the crystallographic form of TiO2 i.e., anatase/rutile mixed phase. TiO2 is an important class of material having various dielectric and electro-optical properties. The existent research presents the electro-optical properties of nematic liquid crystal (NLC) E204 and TiO2 nanocomposites over an extensive range of frequencies. Various important display parameters such as response time, threshold voltage, pretilt angle and activation energy of pristine as well as TiO2 doped composites systems were measured and analyzed. In comparison with the pure, TiO2-doped composite systems has approximately 50% faster response time, owing to its remarkable decline in the relaxation time and activation energy of the LCs. The alteration in the optical intensity of the NLC composites as a function of the concentration of TiO2 nanoparticles (NPs) was also examined. It was established that the optical intensity in nano-nematic composites was decreasing with the concentration of TiO2 NPs. Also, it was observed that an escalation in the TiO2 NPs concentration in NLC composites indicates to an escalation in the birefringence. Probable mechanisms of the interactivity between NLC molecules and TiO2 NPs have been discussed. The current work shows that the TiO2 NPs doping has an encouraging application in the display devices, including other electro-optical as well as photonic applications.

Published in World Journal of Applied Chemistry (Volume 6, Issue 3)
DOI 10.11648/j.wjac.20210603.11
Page(s) 25-35
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Liquid Crystal, Response Time, Pretilt Angle, Threshold Voltage, Birefringence, Activation Energy

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Cite This Article
  • APA Style

    Bhupendra Pratap Singh, Samiksha Sikarwar, Abhishek Kumar Misra, Pankaj Kumar Tripathi, Atul Kumar Srivastava, et al. (2021). Enhanced Electro-optical Properties of Low Viscous Nematic Liquid Crystal Doped with Mixed Phase Anatase/Rutile TiO2 Nanoparticles for Display Applications. World Journal of Applied Chemistry, 6(3), 25-35. https://doi.org/10.11648/j.wjac.20210603.11

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    ACS Style

    Bhupendra Pratap Singh; Samiksha Sikarwar; Abhishek Kumar Misra; Pankaj Kumar Tripathi; Atul Kumar Srivastava, et al. Enhanced Electro-optical Properties of Low Viscous Nematic Liquid Crystal Doped with Mixed Phase Anatase/Rutile TiO2 Nanoparticles for Display Applications. World J. Appl. Chem. 2021, 6(3), 25-35. doi: 10.11648/j.wjac.20210603.11

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    AMA Style

    Bhupendra Pratap Singh, Samiksha Sikarwar, Abhishek Kumar Misra, Pankaj Kumar Tripathi, Atul Kumar Srivastava, et al. Enhanced Electro-optical Properties of Low Viscous Nematic Liquid Crystal Doped with Mixed Phase Anatase/Rutile TiO2 Nanoparticles for Display Applications. World J Appl Chem. 2021;6(3):25-35. doi: 10.11648/j.wjac.20210603.11

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  • @article{10.11648/j.wjac.20210603.11,
      author = {Bhupendra Pratap Singh and Samiksha Sikarwar and Abhishek Kumar Misra and Pankaj Kumar Tripathi and Atul Kumar Srivastava and Meeta Sah and Rajiv Manohar and Kamal Kumar Pandey},
      title = {Enhanced Electro-optical Properties of Low Viscous Nematic Liquid Crystal Doped with Mixed Phase Anatase/Rutile TiO2 Nanoparticles for Display Applications},
      journal = {World Journal of Applied Chemistry},
      volume = {6},
      number = {3},
      pages = {25-35},
      doi = {10.11648/j.wjac.20210603.11},
      url = {https://doi.org/10.11648/j.wjac.20210603.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.wjac.20210603.11},
      abstract = {Organic–inorganic composite based on liquid crystalline and TiO2 nanoparticles were obtained and investigated taking into account the crystallographic form of TiO2 i.e., anatase/rutile mixed phase. TiO2 is an important class of material having various dielectric and electro-optical properties. The existent research presents the electro-optical properties of nematic liquid crystal (NLC) E204 and TiO2 nanocomposites over an extensive range of frequencies. Various important display parameters such as response time, threshold voltage, pretilt angle and activation energy of pristine as well as TiO2 doped composites systems were measured and analyzed. In comparison with the pure, TiO2-doped composite systems has approximately 50% faster response time, owing to its remarkable decline in the relaxation time and activation energy of the LCs. The alteration in the optical intensity of the NLC composites as a function of the concentration of TiO2 nanoparticles (NPs) was also examined. It was established that the optical intensity in nano-nematic composites was decreasing with the concentration of TiO2 NPs. Also, it was observed that an escalation in the TiO2 NPs concentration in NLC composites indicates to an escalation in the birefringence. Probable mechanisms of the interactivity between NLC molecules and TiO2 NPs have been discussed. The current work shows that the TiO2 NPs doping has an encouraging application in the display devices, including other electro-optical as well as photonic applications.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Enhanced Electro-optical Properties of Low Viscous Nematic Liquid Crystal Doped with Mixed Phase Anatase/Rutile TiO2 Nanoparticles for Display Applications
    AU  - Bhupendra Pratap Singh
    AU  - Samiksha Sikarwar
    AU  - Abhishek Kumar Misra
    AU  - Pankaj Kumar Tripathi
    AU  - Atul Kumar Srivastava
    AU  - Meeta Sah
    AU  - Rajiv Manohar
    AU  - Kamal Kumar Pandey
    Y1  - 2021/07/06
    PY  - 2021
    N1  - https://doi.org/10.11648/j.wjac.20210603.11
    DO  - 10.11648/j.wjac.20210603.11
    T2  - World Journal of Applied Chemistry
    JF  - World Journal of Applied Chemistry
    JO  - World Journal of Applied Chemistry
    SP  - 25
    EP  - 35
    PB  - Science Publishing Group
    SN  - 2637-5982
    UR  - https://doi.org/10.11648/j.wjac.20210603.11
    AB  - Organic–inorganic composite based on liquid crystalline and TiO2 nanoparticles were obtained and investigated taking into account the crystallographic form of TiO2 i.e., anatase/rutile mixed phase. TiO2 is an important class of material having various dielectric and electro-optical properties. The existent research presents the electro-optical properties of nematic liquid crystal (NLC) E204 and TiO2 nanocomposites over an extensive range of frequencies. Various important display parameters such as response time, threshold voltage, pretilt angle and activation energy of pristine as well as TiO2 doped composites systems were measured and analyzed. In comparison with the pure, TiO2-doped composite systems has approximately 50% faster response time, owing to its remarkable decline in the relaxation time and activation energy of the LCs. The alteration in the optical intensity of the NLC composites as a function of the concentration of TiO2 nanoparticles (NPs) was also examined. It was established that the optical intensity in nano-nematic composites was decreasing with the concentration of TiO2 NPs. Also, it was observed that an escalation in the TiO2 NPs concentration in NLC composites indicates to an escalation in the birefringence. Probable mechanisms of the interactivity between NLC molecules and TiO2 NPs have been discussed. The current work shows that the TiO2 NPs doping has an encouraging application in the display devices, including other electro-optical as well as photonic applications.
    VL  - 6
    IS  - 3
    ER  - 

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Author Information
  • Liquid Crystal Research Lab, Department of Physics, University of Lucknow, Lucknow, India

  • Department of Physics, Babasaheb Bhimrao Ambedkar University, Lucknow, India

  • Department of Physics, Government Vishwanath Yadav Tamaskar Post-Graduate Autonomous College, Durg, Chhattisgarh, India

  • Liquid Crystal Research Lab, Department of Physics, University of Lucknow, Lucknow, India

  • Liquid Crystal Research Lab, Department of Physics, University of Lucknow, Lucknow, India

  • Shri Jai Narain Misra Post-Graduate College (KKC), Charbagh, Lucknow, India

  • Liquid Crystal Research Lab, Department of Physics, University of Lucknow, Lucknow, India

  • Shri Jai Narain Misra Post-Graduate College (KKC), Charbagh, Lucknow, India

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